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Anales de la Asociación Química Argentina
Print version ISSN 0365-0375
Abstract
BURGOS PACI, M.A. et al. Arrhenius parameters for the thermal decomposition of FC(O)OOC(O)F. An. Asoc. Quím. Argent. [online]. 2005, vol.93, n.4-6, pp.175-182. ISSN 0365-0375.
The gas phase thermal decomposition of FC(O)OOC(O)F was studied at temperatures between 40 and 70 ºC using FTIR spectroscopy to follow the course of the reaction. The decomposition was studied at different partial pressures of NO between 90 to 180 mbar and using N2 to set the total pressure to 1000 mbar. The rate constant fits the Arrhenius equations 
from which the O-O bond energy of (23.9 ± 0.9) kcal mol-1 was obtained.
